Synthesis of borasiloxane-based macrocycles by multicomponent condensation reactions in solution or in a ball mill.
نویسندگان
چکیده
Large macrocycles containing imine and borasiloxane links are obtained in polycondensation reactions of 4-formylbenzeneboronic acid, t-Bu(2)Si(OH)(2), and diamines. The multicomponent reactions can be performed in solution or--advantageously--by mechanochemical syntheses in a ball mill.
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ورودعنوان ژورنال:
- Chemical communications
دوره 49 1 شماره
صفحات -
تاریخ انتشار 2013